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Table 4 Glyphosate, target metabolites, and optimized PRM method parameters. Product ions were used for quantification of the compounds by Xcalibur (v. 3.0.63) data processing module (Quan Browser)

From: Impact of glyphosate and glyphosate-based herbicides on phyllospheric Methylobacterium

Target Analyte

Chemical Formula (M)

Precursor [M-H]− (m/z)

Normalized Collision Energy, eV (NCE)

Product Ions (m/z)

Glyphosate

C3H8NO5P

168.00673

30

78.95902

80.97466

110.00119

124.01685

149.99619

Aminomethylphosphonic Acid (AMPA)

CH6NO3P

110.00125

30

62.96417

78.95901

80.97469

Sarcosine

C3H7NO2

88.04040

30

60.99348

71.01444

87.00938