Assignment | δH | δC | Assignment | δH | δC | ||
---|---|---|---|---|---|---|---|
MetO1 | Phe6 | ||||||
α | 4.78 (1H, m) | 52.11 | α | 4.78 (1H, m) | 54.78 | ||
β | 2.25 (2H, m) | 29.93 | β | 2.95 (2H, m) | 36.01 | ||
γ | 3.02 (2H, m) | 50.09 | γ | 136.61 | |||
ε Me | 2.54 (3H, s) | 38.17 | δ | 129.71 | |||
NH | 7.76 (1H, s) | ε | 129.02 | ||||
C=O | 173.36 | ζ | 126.84 | ||||
Leu2 | NH | 7.45 (1H, m) | |||||
α | 4.51 (1H, m) | 55.82 | C=O | 172.74 | |||
β | 2.25 (1H, m) | 40.38 | Phe7 | ||||
1.97 (1H, m) | α | 4.87 (1H, m) | 54.12 | ||||
γ | 1.62 (1H, m) | 28.55 | β | 3.08 (2H, m) | 34.59 | ||
δ Me | 0.93 (3H, m) | 23.21 | γ | 136.95 | |||
0.88 (3H, m) | 21.56 | δ | 129.97 | ||||
NH | 6.95 (1H, m) | ε | 129.05 | ||||
C=O | 170.77 | ζ | 127.24 | ||||
Ile3 | NH | 7.65 (1H, m) | |||||
α | 4.58 (1H, m) | 56.15 | C=O | 171.14 | |||
β | 1.94 (1H, m) | 36.89 | Leu8 | ||||
γ | 1.69 (2H, m) | 24.34 | α | 4.08 (1H, m) | 54.98 | ||
γ Me | 1.07 (3H, m) | 15.65 | β | 2.15 (1H, m) | 38.73 | ||
δ Me | 0.93 (3H, m) | 11.31 | 1.91 (1H, m) | ||||
NH | 8.06 (1H, br.s) | γ | 1.62 (1H, m) | 25.03 | |||
C=O | 171.40 | δ Me | 0.97 (3H, m) | 23.34 | |||
Pro4 | 0.94 (3H, m) | 21.74 | |||||
α | 3.98 (1H, m) | 59.03 | NH | 7.65 (1H, br.s) | |||
β | 2.28 (1H, m) | 28.78 | C=O | 171.50 | |||
2.06 (1H, m) | |||||||
γ | 1.94 (1H, m) | 24.68 | |||||
1.69 (1H, m) | Ile9 | ||||||
δ | 3.94 (1H, m) | 48.06 | α | 4.34 (1H, m) | 58.71 | ||
3.69 (1H, m) | β | 1.99 (1H, m) | 36.73 | ||||
C=O | 170.69 | γ | 1.51 (2H, m) | 25.37 | |||
Pro5 | γ Me | 0.94 (3H, m) | 16.02 | ||||
α | 4.13 (1H, m) | 61.28 | δ Me | 0.88 (3H, m) | 11.78 | ||
β | 1.94 (2H, m) | 32.11 | NH | 6.74 (1H, m) | |||
γ | 1.51 (1H, m) | 21.99 | C=O | 172.42 | |||
1.14 (1H, m) | |||||||
δ | 3.30 (2H, m) | 47.39 | |||||
C=O | 172.98 |